durusmail: mems-talk: Boron Diffusion
Boron Diffusion
2005-12-27
Boron Diffusion
Tao
2005-12-27
Dear all,
    Merry X'mas.
    I have troubles with Boron diffusion. I do a thermal diffusion with
Borofilm 100 from *EMULSITONE COMPANY*
(http://www.emulsitone.com/bf100.html). The Si wafer is N-type (100)
(1~20ohm cm) with 60nm thermal oxide on the top. I spin on Borofilm 100
(3000rpm for 30seconds)  and use the oxide layer as a mask. I anneal
samples at 1000 degree C for 2 hours and 4 hours under the ambient 97%
N2 + 3% O2, which is recommended by the Emulsitone Company. But after I
etched the oxidation with HF (10%), I found the resistance is about
10ohm/sq everywhere. It seems the Boron penetrated the 60nm oxidation
layer. But from calculation, (see
http://www.batnet.com/enigmatics/semiconductor_processing/selected_shorts/Moistu
re_barriers.html),
the penetration should only be a few nanometers.
    I hope someone can give me some advices on boron diffusion:
       1) Anneal temperature and time
             I need an average contration ~10^18 /cm^3 with a depth
about 0.5~1um
       2) Mask choice: thickness and type
            if it's  thermal oxide, what's the thickness?
            if I use LPCVD to deposite SiO2, what's the thickness?
Thanks a lot. Any advices will be appreciated!

Best
Hongtao

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