One thing to try is to just use CF4, and monitor the emission lines. When your N or CN line vanishes do a brief over etch. You might have a mixture of CF4 and CHF3 to make sure you get an appreciable CN emmission. I am thinking that you have a series of SiO2, Si3N4, Si and so you need some intermediate chemistry that will etch Si3N4 but will chock stoichiometrically on Si. However, that might be making this into too much of a project and you can just use an emission line monitoring to endpoint when the etch reaches the Si under the Si3N4. Ed