If you have a spectrometer you can check that the emission lines match that of Ar using the NIST database: http://www.nist.gov/physlab/data/asd.cfm Pressure will affect the mean free path and hence the energies achieved between collisions. Different energies will access different transition states which ultimately affects the emission observed. On 8 September 2010 14:39, Ranjini Menonwrote: > Dear Debashish, > > when you vary the power or pressure in the system, then the number of > charge particles/ or excited particles and their energy level varies. shift > in color is due to change in available energy levels. > > what sort of plasma system do you have? RF CCP? > > thanks