Right, if you are working with the photonics crystal, I would say that the dimensions are in sub micron range, even if you are in few micron range. Two things, you can try out. The PDMS should not change either doing the curing at room temperature or at high temperature for rapid curing. First, Pour the PDMS in the vacuum as well cure it in vacuum chamber for the best results so that air trap into the holes not let the fill the holes , and second, use appropriate release agent so that while releasing the structures , they are not breaking at the tip to change the height of the structures. Good luck! Parshant Kumar Ph.D.| The Charles Stark Draper Laboratory |MS37|555 Technology Square | Cambridge. MA, 02139-3563|Tel: 617-258-4417|Fax: 617-258-4238 | Email:- pkumar@draper.com |www.draper.com