durusmail: mems-talk: Re: EDP Question (fwd)
Re: EDP Question (fwd)
Re: EDP Question (fwd)
Ash Parameswaran
1996-02-08
Hello Dr. Walsh,

Yes, using EDP to post-process CMOS fabricated chips was my Ph.D., work at
University of Alberta, Canada from 1986-1990. I wrote my doctoral thesis on
that.

One of the device which I built during that time was heater substrates for flow
sensors and that was later converted to a thermal pixel for IR flat panel
display.

Initially we used the recipe given in Dr. Petersen's paper to prepare the EDP
and that infact attacked the Aluminum on the cmos chips. Later I found out that
TRANSENE was supplying EDP under the trade name "Silicon Preferential Etchant
PSE 100". In the data sheets they had indicated Al as a mask for that etchant.
We started buying that and that gave very good results for a while. Later we
found the EDP started attacking Al. We called transene and wanted to find out
what other chemicals they are adding other than EDP to their mixture. We never
got any good leads. Two months later Transene removed the Al as a mask from
their label.

By then we started to tinker around adding Al to EDP in the form of Al-OH so
that the solution is reasonably saturated with Al. That technique is not that
stable. Also, we found out that the silicon content in the Al on CMOS chips
makes a lot of difference on how long Al will stay during EDP etching.

So we decided to do an electroless plating on the exposed Al pads with Nickel
and Gold before we do the EDP etching.

If you can add Al-OH and also adjust the pyrazene content in EDP, then you can
actually get a mixture that doesn't attack Aluminum. This is only good for pure
aluminum. Each CMOS vendor uses different Aluminum alloy for metallization. So
you cannot get consistent results, unless you have lot of time to play with EDP
preparation. Thats why we decided to go for electroless plating.

Sorry for a lengthy answer, hope it clarifies your question. If you need more
information, please do not hesitate to contact me.

Yours sincerely

Ash Parameswaran
School of Engineering Science
Simon Fraser University
Burnaby, BC
Canada V5A 1S6.
Tel: (604) 291-4971
fax: (604) 291-4951


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